Product ID:CITRIKLEEN HD
MSDS Date:06/26/1994
FSC:7930
NIIN:01-314-6133
MSDS Number: CDNQM

PENETONE CORP SUB OF WEST CHEMICAL PRODUCTS INC

74 HUDSON AVENUE
TENAFLY, NJ 07670-1017
US

Emergency Phone: 800-424-9300(CHEMTREC)/201-567-3000

Info Phone: 201-567-3000

Cage: 56883

PENETONE CORP

TENAFLY, NJ 07670 US

Telephone: 201-567-3000

Cage: 56883

D-LIMONENE

CAS: 5989-27-5

RTECS: GW6360000

ETHANOLAMINE

CAS: 141-43-5

RTECS: KJ5775000

OSHA PEL 3 PPM

ACGIH TLV: 3 PPM/6 STEL; 9596

DIETHANOLAMINE (SARA 313) (CERCLA)

CAS: 111-42-2

RTECS: KL2975000

OSHA PEL 3 PPM

ACGIH TLV: 0.46 PPM; 9596

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

VOLITILE ORGANIC CONTENT AS LISTED ON MSDS, 520G/L; VAPOR

RTECS: 9999999VC

Fraction By Weight: NA

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:FLAMMABLE.CAN BE CORROSIVE TO
EYE/SKIN/RESP TRACT.EYE:MAY CAUSE IRRIT/BURNS ON PROL CONTACT.HIGH
VAP CONCEN MAY BE IRRIT.SKIN:FREQ/PROL CONTACT MAY IRRIT/DRY
SKIN,CAUSE DERM/BURNS.INHAL:HI VAP/AEROSOL CONCEN IRRIT/CAUSE
BURNS TO RESP TRACT,HEADACHE,DIZZ,ANESTHESIA,DROWS,UNCONSC,OTHER
CNS EFFECTS.INGEST:SM AMTS (SUPPLE)
Explanation of Carcinogenicity:PER MSDS:DOESN'T CONTAIN ANY CHEM
RECOGNIZED BY STATE OF CA TO CAUASE CAN &/OR BIRTH
DEFECTS/REPRODUCTIVE HARM.
Effects of Overexposure:CORROSIVE TO EYE/SKIN/RESP TRACT. BURNS/IRRIT
EYE/SKIN/RESP TRACT/DIGESTIVE TRACT. DRY
SKIN,DERMATITIS,HEADACHE,DIZZ,ANESTHESIA,DROWSINESS,UNCONSCIOUSNESS
,OTHER CNS EFFECTS.INFLAMM OF LUNGS,INFECTION OF BRONCHI.
Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE EXISTING
DERMATITIS CONDITION.

First Aid:EYE:FLUSH W/LG AMTS OF WATER.SEE PHYSICIAN IMMED.SKIN:FLUSH
W/LG AMTS OF WATER.REMOVE CONTAMIN CLOTH.SKIN IRRIT
DEVELOPS/PERSISTS CONSULT PHYSICIAN.INHAL:REMOVE TO FRESH AIR.ADMIN
OXY/ART RESP AS NEED ED.CALL PHYSICIAN IMMED.INGEST:GIVE PLENTY OF
MILK/WATER.DO NOT INDUCE VOMIT.USE STOMACH PUMP.CALL PHYSICIAN
IMMED.

Flash Point Method:PMCC
Flash Point:125F,52C
Autoignition Temp:Autoignition Temp Text:N/DETR
Lower Limits:N/DETERMINE
Upper Limits:N/DETERMINE
Extinguishing Media:WATER,FOAM, DRY CHEMICAL.
Fire Fighting Procedures:EITHER ALLOW FIRE TO BURN OUT UNDER CONTROLLED
CONDITIONS OR EXTINGUISH W/WATER,FOAM,DRY CHEMICAL.
Unusual Fire/Explosion Hazard:FLAMM LIQ.CAN FORM FLAMM MIXTURES @/OR
ABOVE FLASH POINT.CONTAINERS CAN RUPTURE & EXPLODE UNDER FIRE
CONDITIONS DUE TO PRESSURE & VAP BUILDUP.

Spill Release Procedures:ELIMINATE IGN SOURCES.SM:USE ABSORHBENT
AMTL(TOWELS,ABSORBENT POWDERS).PUT INTO PROPER WASTE DISPO CNTNR
W/LID TIGHTLY COVERED.SOLVT SOAK MATL MAY SPONT
COMBUST.LG:DIKE.RECOVER FREE LIQ,USE ABSORBENT MATL TO DRY
AREA.RINSE W/WATER.PUT IN WASTE CNTNR.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DON'T MIST PRODUCT;USE COARSE SPRAY
ONLY.STORAGE TEMP:AMBIENT.DO NOT STORE >120F.KEEP FROM
FREEZING.KEEP AWAY FROM HEAT SOURCES,OPN FLAME,IGN SOURCES.
Other Precautions:DO NOT STORE NEAR STRONG OXIDANTS.
CERCLA:DIETHANOLAMINE RQ=1LB;RCRA HAZ CLASS:D001,D002;CONTAINS SARA
SEC 313 REPORTABLE CHEMS:DIETHYLENE GLYCOL MONOBUTYL ETHER
<10%,DIETHANOLAMINE <2%.CONTANS PHOTOC HEMICALLY REACTIVE MATL.

Respiratory Protection:AN ORGANIC VAPOR MASK SHOULD BE USED IF TLV IS
EXCEEDED & PARTICLE MASK IF PRODUCT IS SPRAYED.
Ventilation:NONE NEEDED UNDER NORMAL USE CONDITIONS.ENCLSD AREA/LG AMTS
USED USE FANS/OTHER MECH VENTI RECOMMENDED.
Protective Gloves:SOLVENT RESISTANT GLOVES.
Eye Protection:SAFETY GLASSES FOR ALL WORKP CONDITIONS.
Other Protective Equipment:OTHER PROTECTIVE GEAR INCLUDE SPLASH PROOF
GOGG/FACE SHIELD,RUBB BOOTS,APRON,GAUNTLETS,RAIN GEAR DEPENDING ON
PROD USE.
Work Hygienic Practices:LAUNDER CONTAMIN CLOTH BEF REUSE.
Supplemental Safety and Health
HEALTH:OF LIQ MAY BE DRAWN INTO LUNGS BY INGEST/VOMIT-CAUSE
SEVERE/DELAYED HEALTH EFFECTS-LUNGS INFLAMM,BRONCHI
INFECTIONS.INGEST CAUSE IRRIT/BURNS DIGESTIVE TRACT.CHRONIC:INFLAMM
OF MUC MEMB/RESP TRA CT OCCUR UPON PROL BREATH MIST.INGEST LG
D'LIMONENE CAUSE KIDNEY/LIVER DMG IN LAB ANIMALS. DISPO:ENVIRO REG
AGENCY REQMT

HCC:F6
Boiling Pt:B.P. Text:121F,49C
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:=WATER
Vapor Density:=WATER
Spec Gravity:0.97
pH:11.2
Viscosity:NP
Evaporation Rate & Reference:=WATER, ACETONE=1
Solubility in Water:EMULSIFIES.
Appearance and Odor:CLEAR, AMBER LIQUID, WITH CITRUS WINTERGREEN ODOR.
Percent Volatiles by Volume:50
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:ALL IGNITION SOURCES, OPEN FLAMES.
Hazardous Decomposition Products:HAZ COMBUST PROD:SMOKE,FUMES,OXIDES OF
CARBON & NITROGEN.

Waste Disposal Methods:REMOVE PRODUCT FROM WATER SURFACE BY SKIMMING OR
W/SUITABLE ABSORBENTS.PROD CONTAINS SURFACTANTS-WILL CAUSE IT TO
DISPERSE IN WATER.LOCALIZED HI CONCEN OF PROD MAY CAUSE FISH KILLS
BUT NO PERSISTENT/L ONG TERM EFFECTS WILL RESULT.CHECK
W/LOC(SUPPLEME)

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